At the intersection of Main and Parker streets you'd find Orchard Pharmacy
It closed in the late 1980s and was replaced by a series of pizza establishments until about 5 years ago when the entire triangular corner ,including the famous green monster building, was demolished.
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He sold the business which included a small liquor store and joined a new outfit in the Orchard plaza along with the Olde Butcher Shop that was once across the street,but had moved to and survived in the plaza
Together along with additional products it became a supermarket which name I can't recall.
It didn't survive , but it provided the roots for the current supermarket at the site, Save-a-Lot.
Aspirin is about all you can buy there now.
One older pharmacy that existed on 222 Main St. was Paul Mongeau Pharmacy.